Thursday, May 27, 2010

CHANGE OF STATE

Let Us Learn About Boiling point


Matter normally exists in three states: solid, liquid, and gas. A transition from one of these states to another is called a change of state. Two common changes of states are solid to liquid and liquid to gas (and vice versa). These changes can occur when the exchange of heat takes place between the substance and its surroundings.

The change of state from solid to liquid is called melting and from liquid to solid is called fusion. It is observed that the temperature remains constant until the entire amount of the solid substance melts. That is, both the solid and liquid states of the substance coexist in thermal equilibrium during the change of states from solid to liquid. The temperature at which the solid and the liquid states of the substance in thermal equilibrium with each other is called its melting point. It is characteristic of the substance. It also depends on pressure. The melting point of a substance at standard atomspheric pressure is called its normal melting point. Let us do the following activity to understand the process of melting of ice.



Take a slab of ice. Take a metallic wire and fix two blocks, say 5 kg each, at its ends. Put
the wire over the slab as shown in Fig. 11.10. You will observe that the wire passes through
the ice slab. This happens due to the fact that just below the wire, ice melts at lower
temperature due to increase in pressure. When the wire has passed, water above the wire freezes again. Thus the wire passes through the slab and the slab does not split. This phenomenon of refreezing is called regelation

The boiling point of an element or a substance is the temperature at which the vapor pressure of the liquid equals the environmental pressure surrounding the liquid. A liquid in a vacuum environment has a lower boiling point than when the liquid is at atmospheric pressure. A liquid in a high pressure environment has a higher boiling point than when the liquid is at atmospheric pressure. In other words, the boiling point of liquids varies with and depends upon the surrounding environmental pressure and elevation. Different liquids boil at different temperatures.

The normal boiling point of a liquid is the special case in which the vapor pressure of the liquid equals the defined atmospheric pressure at sea level, 1 atmosphere. At that temperature, the vapor pressure of the liquid becomes sufficient to overcome atmospheric pressure and lift the liquid to form bubbles inside the bulk of the liquid


Let Us Learn Nature Of Liquid in our next blog


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