This kind of equilibrium is observed in substances which undergo ionization easily, or in polar substances in which ionization can be considered. Ionic & polar substances are more easily soluble in polar solvents due to ease of ionization taking place in the solvent medium. With the dissolution of ionic & polar substances in the solvent, these solutions become rich in mobile charge carriers (ions) & thus can conduct electricity. Substances, that are capable of conducting electricity are said to be as electrolytes while those substances which are non-conducting said to be as non-electrolytes.
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